You searched for: “most superlative”
superlative (adjective), more superlative, most superlative
1. A reference to the highest quality of something that is surpassing all others: Monroe had superlative technical advice when he was asked to show Jim how to use his new computer.
2. In grammar, pertaining to, or noting the highest degree of the comparison of adjectives and adverbs: Here are examples of words that show superlative forms:
  • small = smallest
  • good = best
  • carefully = most carefully
3. Exceeding what is normal; such as, exceptional language or style: Karin's superlative manner of dressing and speaking was admired by her friends because she got along so well with everyone and her appearance was very attractive.
4. Descriptive of an individual or something that is considered to be one of the best: Bill's superlative acting abilities made the drama much more successful.
5. The utmost degree: Ted's new car was described as the most superlative model in its class because no other vehicle had such a high degree of quality!
A reference tp high quality or being supreme.
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Did you notice that the image above indicates that it is identified as an adjective; however, isn't the speaker using it as if it were a noun?

Relating to being excessive or exaggerated.
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This entry is located in the following units: later-, lateral-, -late, -lat, -lation, -lative (page 2) super-, supra-, sur- (page 9)
Word Entries at Get Words: “most superlative”
superlative, more superlative, most superlative
Referring to the greatest degree of excellence, the highest quality, or anything that is much better than normal. (2)
This entry is located in the following unit: Word a Day Revisited Index of Cartoons Illustrating the Meanings of Words (page 75)